赖南君, 闻一平, 傅波, 徐俊芳, 王思遥, 王爱香. 复合交联聚合物弱凝胶体系的研制与性能评价[J]. 石油钻采工艺, 2014, 36(3): 87-91. DOI: 10.13639/j.odpt.2014.03.022
引用本文: 赖南君, 闻一平, 傅波, 徐俊芳, 王思遥, 王爱香. 复合交联聚合物弱凝胶体系的研制与性能评价[J]. 石油钻采工艺, 2014, 36(3): 87-91. DOI: 10.13639/j.odpt.2014.03.022
LAI Nanjun, WEN Yiping, FU Bo, XU Junfang, WANG Siyao, WANG Aixiang. Development and property evaluation of compound cross-linking polymer weak gel system[J]. Oil Drilling & Production Technology, 2014, 36(3): 87-91. DOI: 10.13639/j.odpt.2014.03.022
Citation: LAI Nanjun, WEN Yiping, FU Bo, XU Junfang, WANG Siyao, WANG Aixiang. Development and property evaluation of compound cross-linking polymer weak gel system[J]. Oil Drilling & Production Technology, 2014, 36(3): 87-91. DOI: 10.13639/j.odpt.2014.03.022

复合交联聚合物弱凝胶体系的研制与性能评价

Development and property evaluation of compound cross-linking polymer weak gel system

  • 摘要: 由于弱凝胶调驱体系抗剪切性能弱而限制了其在油藏中的应用,以共聚物丙烯酰胺/ 丙烯酸/N- 乙烯基吡咯烷酮为主剂,加入甲醛– 苯酚复合交联剂和高温稳定剂,制备了调驱性能较好的弱凝胶体系。考察了聚合物质量浓度、稳定剂质量浓度、交联剂/ 聚合物质量比、交联剂配制摩尔比、温度、pH 值以及矿化度对成胶性能的影响。确定了弱凝胶体系的最佳使用条件: 聚合物AM/AA/NVP 质量浓度2 000 mg/L,交联剂/ 聚合物质量比2/1 000,交联剂(甲醛/ 苯酚)摩尔比4∶1,稳定剂(硫脲)质量浓度100 mg/L,pH 值为7,温度60 ℃。室内调驱性能评价表明,该体系具有良好的抗剪切性能,黏度保留率达到91.38%,同时封堵率在99% 以上,突破压力大于7 MPa,并且还具有一定的选择封堵能力,剖面改善率达到80% 以上。

     

    Abstract: The weak shear resistance of weak gel profile controlling and flooding system limits its application in reservoirs, we prepared a weak gel system with favorable profile controlling and flooding performance with AM/AA/NVP as the main agent and added Phenol–formaldehyde as cross-linking agent and temperature stabilizer. We studied the effects of polymer concentration, stabilizer concentration, crosslinker/polymer proportion, crosslinker concentration, temperature, pH and salinity on the gelling property. The optimum conditions for preparing the weak gel system were identified as follows: concentration of polymer (AM/AA/NVP): 2 000 mg/L; mass ratio of crosslinker/polymer: 2/1 000; proportion of crosslinker (formaldehyde/phenol): 4∶1; concentration of stabilizer: 100 mg/L; pH of the system: 7; and suitable temperature 60 ℃. The in-house evaluation on profile controlling and flooding performance shows that the system has good shear resistance, its viscosity retention rate is up to 91.38%, and its plugging rate is above 99%, its breakthrough pressure is greater than 7 MPa and has certain selective plugging capability, and the sectional improvement rate is over 80%.

     

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