高珊珊,余吉良,唐雅娟,赵董艳,张田田,王志强,杜慧丽. 临界温度下不同凝胶体系适应性研究及配方优化[J]. 石油钻采工艺,2020,42(6):779-783. DOI: 10.13639/j.odpt.2020.06.019
引用本文: 高珊珊,余吉良,唐雅娟,赵董艳,张田田,王志强,杜慧丽. 临界温度下不同凝胶体系适应性研究及配方优化[J]. 石油钻采工艺,2020,42(6):779-783. DOI: 10.13639/j.odpt.2020.06.019
GAO Shanshan, YU Jiliang, TANG Yajuan, ZHAO Dongyan, ZHANG Tiantian, WANG Zhiqiang, DU Huili. Adaptability study and formula optimization of different gel systems under the critical temperature[J]. Oil Drilling & Production Technology, 2020, 42(6): 779-783. DOI: 10.13639/j.odpt.2020.06.019
Citation: GAO Shanshan, YU Jiliang, TANG Yajuan, ZHAO Dongyan, ZHANG Tiantian, WANG Zhiqiang, DU Huili. Adaptability study and formula optimization of different gel systems under the critical temperature[J]. Oil Drilling & Production Technology, 2020, 42(6): 779-783. DOI: 10.13639/j.odpt.2020.06.019

临界温度下不同凝胶体系适应性研究及配方优化

Adaptability study and formula optimization of different gel systems under the critical temperature

  • 摘要: 为了满足现场深部调驱的需求,研究适用于临界温度(65~75 ℃)条件下的凝胶调驱体系配方。采用室内实验评价方法对聚丙烯酰胺(HPAM)-有机铬和聚丙烯酰胺(HPAM)-酚醛树脂共2种常用凝胶体系在70 ℃条件下的适应性进行了分析与评价。研究结果表明,酚醛树脂凝胶比有机铬凝胶的成胶黏度高,黏弹性模量大,说明附着力和抗剪切能力强;成胶的浓度下限低,可大大降低调驱成本。然而,酚醛树脂凝胶存在交联速度慢、交联时间过长(120~140 h)等问题,因此引入金属离子增加交联反应类型,将交联时间缩短至48 h;得到了适用于临界温度下的可动凝胶体系配方:聚合物浓度为1 200 mg/L,交联剂浓度为1 300 mg/L,促胶剂浓度为50 mg/L。对应凝胶体系的交联时间为48 h,成胶黏度为2 100 mPa · s,70 ℃条件下,恒温考察90 d,黏度保持率达到70%以上,并且仍保持较好的黏弹性,未出现破胶、析水现象,说明体系长期稳定性良好。

     

    Abstract: In order to meet the demand of field in-depth flooding control, this paper studied the formula of gel flooding control system suitable for the critical temperature of 65-75 ℃. The adaptability of two commonly used gel systems, i.e., polyacrylamide (HPAM)-organic chromium and HPAM-phenolic resin under 70 ℃ were analyzed and evaluated by means of the laboratory experimental evaluation method. The results show that compared with organic chromium gel, phenolic resin gel has higher gelling viscosity and larger viscoelastic modulus, indicating its adhesive force and shear resistance are strong. And the lower limit of its gelling concentration is low, which can reduce the flooding control cost greatly. However, phenolic resin gel has the disadvantages of low crosslinking speed and long crosslinking time (120-140 h). To solve these problems, metallic ions were introduced to increase the types of crosslinking reaction so as to shorten the crosslinking time to 48 h. Finally, the formula of the movable gel system suitable for the critical temperature was obtained as follows: polymer concentration 1 200 mg/L, crosslinker concentration 1 300 mg/L and crosslinking promoter concentration 50 mg/L. The crosslinking time and gelling viscosity of the corresponding gel system are 48 h and 2 100 mPa · s, respectively. It is observed for 90 d under the constant temperature of 70 ℃. It is shown that the viscosity maintenance rate is over 70 %, the viscoelasticity is still kept better and no gel breaking or free water occurs, indicating the long-term stability of this system is good.

     

/

返回文章
返回