刘平江,王波,闫文华,等. 高弹性温敏型延迟吸水膨胀堵漏剂的合成与评价[J]. 石油钻采工艺,2026,48(1):44-51. DOI: 10.13639/j.odpt.202507036
引用本文: 刘平江,王波,闫文华,等. 高弹性温敏型延迟吸水膨胀堵漏剂的合成与评价[J]. 石油钻采工艺,2026,48(1):44-51. DOI: 10.13639/j.odpt.202507036
LIU Pingjiang, WANG Bo, YAN Wenhua, et al. Synthesis and evaluation of a high-elasticity and temperature-sensitive delayed water-swelling plugging agent[J]. Oil Drilling & Production Technology, 2026, 48(1): 44-51. DOI: 10.13639/j.odpt.202507036
Citation: LIU Pingjiang, WANG Bo, YAN Wenhua, et al. Synthesis and evaluation of a high-elasticity and temperature-sensitive delayed water-swelling plugging agent[J]. Oil Drilling & Production Technology, 2026, 48(1): 44-51. DOI: 10.13639/j.odpt.202507036

高弹性温敏型延迟吸水膨胀堵漏剂的合成与评价

Synthesis and evaluation of a high-elasticity and temperature-sensitive delayed water-swelling plugging agent

  • 摘要: 针对目前吸水膨胀类堵漏剂体积膨胀速率不可控、承压能力差等问题,以丙烯酰胺(AM)和丙烯酸羟乙酯(HEA)作为单体,天然淀粉为接枝材料,N,N′-亚甲基双丙烯酰胺(MBA)为交联剂,并引入膨润土作为无机刚性粒子,通过自由基水溶液聚合法研发出高弹性温敏型延迟吸水膨胀堵漏剂(PHSAP)。研究结果表明,温度和酸碱度是调控PHSAP吸水膨胀行为的关键因素。低温酸性(30 ℃、pH为3)条件下24 h吸水质量倍数仅为0.47倍,而在高温碱性(85 ℃、pH为10)条件下24 h吸水质量倍数可达17.19倍。同时延迟吸水膨胀特性,能助力堵漏材料顺利进入漏失通道,且便于泵送施工。此外,PHSAP具备良好的弹性形变能力与较高的抗压强度,压缩应变达82.56%时承压为2.14 MPa。热重分析表明,PHSAP在201 ℃以内没有明显质量损失,分子链及官能团热稳定性良好。封堵实验证实,PHSAP构建的堵漏浆在不同粒径石英砂模拟的地层孔隙与裂缝中能形成有效封堵,承压能力不低于5 MPa。上述性能表明,PHSAP在应对深井高温地层的复杂漏失问题时,具有良好的应用前景。

     

    Abstract: To address the issues of uncontrollable volume expansion rate and worse pressure-bearing capacity of existing water-swelling plugging agent, a high-elasticity and temperature-sensitive delayed water-swelling plugging agent (PHSAP) was developed through free radical aqueous solution polymerization using acrylamide (AM) and hydroxyethyl acrylate (HEA) as monomers, natural starch as grafting material, N,N'-methylenebisacrylamide (MBA) as crosslinking agent, and bentonite introduced as inorganic rigid particles. The research results indicate that temperature and pH are key factors regulating the water-swelling behavior of PHSAP. Under low-temperature acidic conditions (30 ℃, pH 3), the water absorption mass ratio is only 0.47 times within 24 hours, whereas under high-temperature alkaline conditions (85 ℃, pH 10), it can reach 17.19 times within 24 hours. Additionally, the delayed water-swelling characteristics facilitate the smooth entry of the plugging material into the leakage channel and ease pumping operations. Furthermore, PHSAP exhibits sound elastic deformation capacity and high compressive strength, maintaining a pressure of 2.14 MPa at the compressive strain of 82.56%. Thermogravimetric analysis shows that PHSAP has no significant mass loss below 201 ℃, indicating excellent thermal stability of its molecular chains and functional groups. The plugging experiments confirmed that the plugging slurry constructed with PHSAP can achieve effective sealing in formation pores and fractures simulated by quartz sand of different particle sizes, with a pressure-bearing capacity of no less than 5 MPa. These properties of PHSAP suggest that PHSAP has promising application prospects in addressing complex leakage issues in high-temperature formations of deep wells.

     

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